This article explores the composition of the personal social networks and their interrelation with the family context of recently arrived refugees in Germany. Using the Refugee Sample of the German Socio-Economic Panel (2017) and performing logistic regression analyses, the findings suggest that refugees living without their partner, children, or extended family in Germany are more likely to have at least one close non-kin confidant. The same holds true for inter-ethnic contacts. Moreover, the results show that also opportunity structures like the workplace or leisure-time activities matter. As male and female refugees have different family arrangements, differences by sex emerge.